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Optically Active Titanium Complexes Containing Linked Amido-cyclopentadienyl Ligands: Their Use as Asymmetric Hydrogenation Catalysts

✍ Scribed by Okuda, Jun ;Verch, Sabine ;Spaniol, Thomas P. ;Stürmer, Rainer


Publisher
Wiley (John Wiley & Sons)
Year
1996
Tongue
English
Weight
389 KB
Volume
129
Category
Article
ISSN
0009-2940

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Optically active titanium complexes cont
✍ Jun Okuda; Sabine Verch; Rainer Stürmer; Thomas P. Spaniol 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 121 KB 👁 2 views

Optically active titanium complexes Tieta5:eta1-C5R4SiMe2NC6H10 (OCH2Ph)-2Cl2 (R = H, Me), containing a cyclopentadienyl ligand linked to the chiral trans-2-benzyloxycyclohexylamido group, were synthesized and characterized in both enantiomerically pure forms. A single crystal X-ray structure analys