Optically Active Mixed Phthalocyaninato–porphyrinato Rare-Earth Double-Decker Complexes: Synthesis, Spectroscopy, and Solvent-Dependent Molecular Conformation

Optically Active Mixed Phthalocyaninato–

Optically Active Mixed Phthalocyaninato–Porphyrinato Rare-Earth Double-Decker Complexes: Synthesis, Spectroscopy, and Solvent-Dependent Molecular Conformations

✍ Xiaomei Zhang; Atsuya Muranaka; Wei Lv; Yuexing Zhang; Yongzhong Bian; Jianzhuan 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 440 KB 👁 2 views

## Abstract Reaction between the optically active metal‐free phthalocyanine with a π system with noncentrosymmetrical __C~2v~__ symmetry ((__S__)‐ and (__R__)‐H~2~{Pc(OBNP)~2~}; OBNP=binaphthylphthalocyanine) and half‐sandwich complexes [M^III^(acac)(TClPP)] (M=Y, Eu; TClPP=__meso__‐tetrakis(4‐chlo