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Optically active methacrylic polymers bearing side-chain conjugated azoaromatic chromophores

✍ Scribed by L Angiolini; D Caretti; L Giorgini; E Salatelli


Book ID
117537286
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
163 KB
Volume
115
Category
Article
ISSN
0379-6779

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Synthesis and chiroptical properties of
✍ Luigi Angiolini; Daniele Caretti; Loris Giorgini; Elisabetta Salatelli 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 225 KB 👁 2 views

Novel optically active polymethacrylates, namely poly[(S)-3-methacryloyloxy-1-(4-azobenzene)pyrrolidine] and poly[(S)-3-methacryloyloxy-1-(4Ј-nitro-4-azobenzene)pyrrolidine], have been synthesized by radical polymerization of the corresponding monomers, prepared in turn through a synthetic route pre

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## Abstract The synthesis of three novel optically active monomers containing a side‐chain chiral moiety linked to a photochromic bisazoaromatic chromophore, such as (__S__)‐3‐methacryloyloxy‐1‐[4′‐phenylazo‐(4‐azobenzene)]‐pyrrolidine [(__S__)‐**MPAAP**], (__S__)‐3‐methacryloyloxy‐1‐[4′‐cyanopheny

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## Abstract The synthesis of a novel optically active methacrylic monomer containing in the side chain the (__S__)‐3‐hydroxy‐__N__‐phenyl pyrrolidine ring linked to a 4‐cyanophenylazocarbazole moiety [(__S__)‐**MCAPP**‐**C**] and of the analogous achiral monomer (**MCAPE‐C**) is described. Both the

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## Abstract The photochromic and photoresponsive properties of a series of optically active azoaromatic polymers, containing in the side chain the rigid (__S__)‐ and/or (__R__)‐hydroxysuccinimide residue, have been investigated in solution and in the solid state as thin films by observing the __tra