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Optically active ethylenediamine(1,4,8,11-tetraazacyclotetradecane)cobalt(III) and ethylenediamine

✍ Scribed by Matsuo Nonoyama; Osamu Hirai


Book ID
104138122
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
162 KB
Volume
54
Category
Article
ISSN
0020-1693

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The cis/trans-isomerism on cobalt(III) c
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The X-ray structure determinations show that 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic) acid H 4 L forms both cis-and trans-O,O isomeric complexes with Co(III). Orientation of the other donor atoms indicates the formation of cis-O1,O2-trans-N1,N8-cis-O1, ]. The kinetically preferred