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Optically Active Bipyridines in Asymmetric Catalysis

✍ Scribed by Dr. Carsten Bolm; Priv.-Doz. Dr. Margareta Zehnder; Dr. Daniel Bur


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
341 KB
Volume
29
Category
Article
ISSN
0044-8249

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Preparation of Optically Active α-Amino[
✍ Patrick Liptau; Ludger Tebben; Gerald Kehr; Birgit Wibbeling; Roland Fröhlich; G 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 288 KB

## Abstract Treatment of 1,1′‐diacetylferrocene (**4**) with dimethylamine and TiCl~4~ yielded the unsaturated dimethylamino‐substituted [3]ferrocenophane product **5**. Its catalytic hydrogenation gave the corresponding saturated [3]ferrocenophane system **6** (__trans__/__cis__ ≈︁ 7:1). The __rac

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## Abstract Treatment of 1,1′‐diacetylferrocene (**4**) with dimethylamine and TiCl~4~ yielded the unsaturated dimethylamino‐substituted [3]ferrocenophane product **5**. Its catalytic hydrogenation gave the corresponding saturated [3]ferrocenophane system **6** (__trans__/__cis__ ≈︁ 7:1). The __rac