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Optically Active Bimetallic Complexes with a Tantalum Atom as a Chiral Center. Synthesis, Characterization, and X-ray Structures of Two Diastereoisomers: Cp‘CpTa(CO)(μ-PMe 2 )W(CO) 4 L (Cp‘ = 1- t Bu-3,4-Me 2 -C 5 H 2 ; L* = ( R )-(+)-Phenyl( o -anisyl)methylphosphine (PAMP))

✍ Scribed by Sauvageot, Philippe; Blacque, Olivier; Kubicki, Marek M.; Jugé, Sylvain; Moïse, Claude

No coin nor oath required. For personal study only.

Optically Active Bimetallic Complexes with a Tantalum Atom as a Chiral Center. Synthesis, Characterization, and X-ray Structures of Two Diastereoisomers: Cp‘CpTa*(CO)(μ-PMe 2 )W(CO) 4 L* (Cp‘ = 1- t Bu-3,4-Me 2 -C 5 H 2 ; L* = ( R )-(+)-Phenyl( o -anisyl)methylphosphine (PAMP))