Optically active amines containing no asymmetric atom

✍ Scribed by Janson, S. E. ;Pope, W. J.

• Publisher: Wiley (John Wiley & Sons)
• Year: 1932
• Weight: 335 KB
• Volume: 51
• Category: Article
• ISSN: 0368-4075
• DOI: 10.1002/jctb.5000511503

✦ Synopsis

According TO present views on niolcculiir configurnt,ion, cert iiiii tl cri va t ivcs of s p irorydo-Ii cpt n n c sh oul tl I )c rcsolviible into opticidly iictive coitipoticnts iiltlioiigh no risyninictric atom is present in the molcculc. Ainong these is Fecht's .s~~iroc~rIo-licptiiiic~liciirl~oxylic iicitl ( t i ) froiii which Uiickcr iiiirl Scliurink Itiivc sepiirntctl thr dcstrorotritory component of low molccnlnr rotation (Rcc., 1031,50, !El).

.-\ rcrnrirkiilde mcthod for rcpliichg the ciirlwsyl group