𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Optically active alcohols: Resolution and synthesis from asymmetric reduction of prochiral ketones

✍ Scribed by Hu Xian-ming; Liu Jun


Publisher
Wuhan University
Year
1999
Tongue
English
Weight
390 KB
Volume
4
Category
Article
ISSN
1007-1202

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


ChemInform Abstract: Optically Active Al
✍ Xian-ming Hu; Jun Liu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 25 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Enantiospecific reduction of prochiral k
✍ Bogdan Jarosz; Prof. Dr. Antoni Siewiński 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 501 KB

## Abstract The culture of __Nigrospora oryzae__ reduces twelve prochiral ketones of homo‐ and heteroaromatic type (acetophenone, 3‐ and 4‐methylacetophenone, 4‐nitroacetophenone, propiophenone, 2‐acetylnaphtha‐lene, 2‐acetyltiophene, 2‐ and 4‐acetylpyridine, __α,α,α__‐trifluoroacetophenone, α‐tetr

Stereoselective synthesis of optically a
✍ Kazuya Okano; Kunihiko Murata; Takao Ikariya 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 69 KB

A chiral Ru(II) complex, RuCl[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenyl-ethylenediamine](p-cymene), serves as an efficient catalyst for asymmetric transfer hydrogenation of 2-acetylpyridine with a substrate to catalyst molar ratio of 200-1000 with HCOOH as a hydrogen source to give (S)-1-(2-pyridyl)e

Catalytic asymmetric borane reduction of
✍ Zhou Yong-Gui; Hou Xue-Long; Dai Li-Xin 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 264 KB 👁 1 views

Easily available D-(+)-camphor-derived chiral mercapt\*alcohols 2 and 3 were employed for catalytic asymmetric borane reduction of aromatic ketones. Moderate enantioselectivities with e.e. 20.2-72.1% were obtained with 10 mol% catalyst. Opposite asymmetric induction was achieved' when mercaptc-alcoh