Optical spectra of C60 and C70 complexes: their similarities and differences
β Scribed by Andrzej Graja; Jean-Pierre Farges
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 267 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1616-301X
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β¦ Synopsis
Some possible uses of vibrational and electronic spectroscopies in characterising the basic interactions in C 60 and C 70 complexes are pointed out. We report on the wealth of infrared spectra of (usually) single crystals of C 60 and C 70 clathrates and complexes with organic donors. The changes in the spectral parameters of the complexes in comparison with those of the neutral fullerene molecules are attributed to redistribution of the charge on the spherical C 60 or elongated C 70 molecules in their compounds. Some general considerations on the origin of the IR, NIR, VIS and UV spectral variations are also given. *
π SIMILAR VOLUMES
Resonant electron capture by C 60 and C 70 was studied and it was established that long-lived (i.e. mass spectrometrically observable) parent negative ions are formed within an extremely broad energy region (0-14 eV). It has been shown that effective yield curves of C 60 -and C 70 -in the thermal en
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C 60 and C 70 adducts containing spacer-linked phenyl (BK1), are given. Electrochemical and optoelectrochemical studies were undertaken by using cyclic voltammetry and 9-anthracenyl (BK2), 4-(9-anthracenyl)phenyl (BK3), and 1pyrenyl groups (BE1 and FE1) have been studied. Two spectroelectrochemical