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Optical spectra of C60 and C70 complexes: their similarities and differences

✍ Scribed by Andrzej Graja; Jean-Pierre Farges


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
267 KB
Volume
8
Category
Article
ISSN
1616-301X

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✦ Synopsis


Some possible uses of vibrational and electronic spectroscopies in characterising the basic interactions in C 60 and C 70 complexes are pointed out. We report on the wealth of infrared spectra of (usually) single crystals of C 60 and C 70 clathrates and complexes with organic donors. The changes in the spectral parameters of the complexes in comparison with those of the neutral fullerene molecules are attributed to redistribution of the charge on the spherical C 60 or elongated C 70 molecules in their compounds. Some general considerations on the origin of the IR, NIR, VIS and UV spectral variations are also given. *


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