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Optical rotatory properties and conformations of esters and polyesters of trans-1,2-cyclohexanedicarboxylic acid

✍ Scribed by Overberger, C. G. ;Montaudo, G. ;Furuyama, Toshiuki ;Goodman, Murray

Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
468 KB
Volume
31
Category
Article
ISSN
0449-2994

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✦ Synopsis

Abstract

The conformational preferences of trans‐1,2‐cyclohexanedicarboxylic acid (1,2‐CH) and ester derivatives have been studied. The optical rotatory properties of these compounds are discussed in comparison with those of other cyclic dicarboxylic acids. A stereoregular polymer, poly[ethylene‐(+)‐trans‐1,2‐cyclohexane dicarboxylate] (1,2‐CHPE) has been synthesized, and its properties are compared with those of model compounds.

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