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Optical properties of disubstituted polyacetylene

โœ Scribed by I.I. Gontia; S. Frolov; M. Liess; K. Yoshino; Z.V. Vardeny


Book ID
117542130
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
411 KB
Volume
101
Category
Article
ISSN
0379-6779

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Poly(phenyl vinyl sulfoxide) (PVSO) is a soluble precursor to polyacetylene (PA). Upon thermal elimination, the thermally labile PVSO can be converted to PA by undergoing a 'zipper-like' 5-members cyclic sigmatropic elimination process. Both PVSO and its copolymers can be synthesized via anionic pol