Two electronic bands arising from the tt + 2e and tt \* 3t2 transitions are observed in the region ==360 nm and ~250 nm in alkali halide crystals doped with CrzO;-. These bands split and also show well resolved fine structure at.77"K. The fme structure is explained on the hasis of vibrational freque
โฆ LIBER โฆ
Optical properties of dichromate centers in some lattices
โ Scribed by B.V.R. Chowdari; Y. Ravi Sekhar
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 373 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The optical absorption spectra of &chromate centers in potassium ahun, ammonium alum, KDP and ADP have been studied. Different-molecular orbital schemes have been considered to explain the observed specrrum and the scheme proposed by Vie and Gray has been preferred. Coupling between the electronic states and the totally symmetric stretching vibrational mode is found to be present.
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