Optical Probes for Monitoring Intercalation and Exfoliation in Melt-Processed Polymer Nanocomposites

✍ Scribed by Paul H. Maupin; Jeffrey W. Gilman; Richard H. Harris Jr.; Severine Bellayer; Anthony J. Bur; Steven C. Roth; Marius Murariu; Alexander B. Morgan; Joseph D. Harris

• Book ID: 102493320
• Publisher: John Wiley and Sons
• Year: 2004
• Tongue: English
• Weight: 178 KB
• Volume: 25
• Category: Article
• ISSN: 1022-1336
• DOI: 10.1002/marc.200300262

✦ Synopsis

Abstract

Summary: Laser‐induced fluorescence spectroscopy of the optical probe Nile Blue A in polymer clay nanocomposites is described. Concentration quenching of the fluorescence dominates the probe behavior until the clay platelets are physically separated by polymer intercalation. Further separation into an exfoliated structure results in an intense increase in probe fluorescence. Preliminary results indicate the ability to discriminate between intercalated and exfoliated structures in nanocomposites formed by melt processing.

Polyamide 6 nanocomposites: Purple, 1 minute processing (left). Red, 7 minute processing (right).

magnified imagePolyamide 6 nanocomposites: Purple, 1 minute processing (left). Red, 7 minute processing (right).