We describe the results of optical-optical double-resonance spectroscopy of Cl2 on the 1,(3Pt)+-(hvl)-A%( 1,) + (hu, )-X 'Zi transition. The state-selective transition from the ground state of Cl2 to the A 'lI( I,) state was observed by scanning the pump laser ( hu, ) frequency, while furing the pro
Optical-optical double resonance spectroscopy of Cl2: Analysis of the 1g(3P2)-A3Π(1u) system
✍ Scribed by Takashi Ishiwata; Atsushi Ishiguro; Kinichi Obi
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 777 KB
- Volume
- 147
- Category
- Article
- ISSN
- 0022-2852
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Optical-optical double resonance spectroscopy was used to study the 1 g ( 3 P 1 ) ion-pair state of I 2 correlating to I -( 1 S) + I + ( 3 P 1 ) at the dissociation limit. We gained access to the 1 g ( 3 P 1 ) state though the A 3 (1 u ) state in the (1 + 1) photon-excitation scheme. The pump laser
We report the analysis of the H1 u ( 3 P 1 ) state of I 2 by optical-optical double resonance. This state lies in the second tier of ion-pair states and its observation was achieved by using the (1 ϩ 2) photoexcitation sequence using the A 3 ⌸ 1u state as an intermediate. The molecular parameters we
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