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Optical metal-to-ligand charge-transfer of 2,2′-bipyridyl complexes of antimony(III) and bismuth(III)

✍ Scribed by Horst Kunkely; Alois Paukner; Arnd Vogler


Book ID
108429083
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
232 KB
Volume
8
Category
Article
ISSN
0277-5387

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Optical ligand-to-ligand charge transfer
✍ R. Benedix; H. Hennig; H. Kunkely; A. Vogler 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 355 KB

The electronic structure and the optical ligand-to-ligand charge transfer (LLCT) of the pseudotetrahedral complex Zn(2,2'bipyridyl) (3,4-tolueneditbiolate) is interpreted on the basis of EHT calculations. By comparison with square-planar complexes, it is shown that the extent of electron delocalizat