Optical indications of heterogeneous distribution of equilibrated solvated electrons in liquid and glassy ammonia-methanol solutions

Electrolyte solutions in liquid ammonia—

Electrolyte solutions in liquid ammonia—x. A cyclic voltammetric examination of electron transfer between solvated ruthenium(III) and ruthenium(II) cations, and anodic passivation of platinum electrodes

✍ J. Bernard Gill; Michael Hall; Norman Taylor 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 564 KB

Single electron transfer between the hexammine cations of Ru(III) and Ru(I1) at a Pt metal electrode in liquid ammonia closely follows Nemstian behaviour during the lirst voltammetric cycle if the voltage sweep rate is tow. The redox electrode based on the Ru(III)/Ru(II) couple at a Pt metal surface