Optical Configurations of Complexes of Amino-acids with Cobalt(III)
โ Scribed by GILLARD, R. D.
- Book ID
- 109656415
- Publisher
- Nature Publishing Group
- Year
- 1967
- Tongue
- English
- Weight
- 343 KB
- Volume
- 214
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/214168a0
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๐ SIMILAR VOLUMES
## Absbsct-A method for comparing the optical configurations of carboxylic acids is outlined, using their compkxu with the pentamrninecobalt (III) residue. The spectrqic basis of this method is outlined, and other methods for relating configurations using metal complexes are disused from the spect
&oton magnetic resonance spectra were measured for some cobalt(M) amino acid complexes in D20 and in ammonia solution [I ] . In carboxylato coordinated [Co(NHJ500CCH(R)NHS] 3' compounds in DzO, the chsmical shifts of amino acid hydrogens are close to those of the free amino acid in the dipolar form,