Optical activity of nonrigid molecules
β Scribed by J. Philippot; I. Sengers
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 152 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0020-7608
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β¦ Synopsis
Abstract
The LonguetβHiggins group is used to obtain an alternative formulation of a criterion for optical activity of nonrigid molecules recently given by Frei and GΓΌnthard.
π SIMILAR VOLUMES
## Abstract Starting from the concept of a totally flexible molecule, rigidity is introduced by restricting progressively the allowed permutations. Each nonrigid isomer is then characterized by its LonguetβHiggins group β of allowed permutation inversions. For a given β all nonrigidity types corres
Recent progress in the use of Raman optical activity (ROA) to study the stereochemical properties of biological molecules is described. The basic experimental, theoretical, instrumental and calculational methodology of backscattering ROA is presented together with examples of applications to amino a