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Optical activity in mixed-ligand terbium complexes containing 5-sulfosalicyclic acid and chiral hydroxycarboxylic acids

✍ Scribed by Robert A. Copeland; Harry G. Brittain

Book ID
108428252
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
559 KB
Volume
1
Category
Article
ISSN
0277-5387

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## Abstract The enantiopure complexes **3a** and **3b** [Rh(NBD)(P,S)]^+^BF~4~^βˆ’^ [P,S = (__S__)‐2‐(diphenylphosphanyl)‐2′‐(methylthio)‐1,1′‐binaphthalene (**a**); (__S__)‐2‐(diphenylphosphanyl)‐2′‐(isopropylthio)‐1,1′‐binaphthalene (**b**)] have been prepared from [Rh(NBD)(THF)~2~]^+^BF~4~^βˆ’^ by r