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Optical activity due to isotopic substitution. Vibrational circular dichroism and the absolute configurations of .alpha.-deuterated cyclohexanones

✍ Scribed by Polavarapu, Prasad L.; Nafie, Laurence A.; Benner, Steven A.; Morton, Thomas Hellman

Book ID: 127371505
Publisher: American Chemical Society
Year: 1981
Tongue: English
Weight: 709 KB
Volume: 103
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00408a012

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## Abstract The use of isotopic difference spectra in vibrational optical activity is demonstrated as a supplemental aide in determining the absolute configuration of chiral molecules. It is shown that IR and VCD difference spectra associated with isotopic substitution observed in experimental spec