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Optical absorption and luminescence spectroscopy of bis(acetato)hydroxobis(1,4,7-trimethyl-1,4,7-triazacyclononane)dichromium(3+) perchlorate and bis(acetato)hydroxobis(1,4,7-trimethyl-1,4,7-triazacyclononane)chromiumzinc(2+) perchlorate hemihydrate

✍ Scribed by Reber, Christian; Guedel, Hans U.; Buijs, Maarten; Wieghardt, Karl; Chaudhuri, Phalguni


Book ID
126834773
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
835 KB
Volume
27
Category
Article
ISSN
0020-1669

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HigIl-resolution absorption, iuminesccnce, Zeeman and MCD experiments were performed cm sir& crystals of the title compound. The singlet-tripiet and trip&t-quintet exchange splittings in the ground state are 138 and 267 cm-'. respectively. The corresponding exchange parameters are 2J= -128 cm-' andj