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Opening of Tartrate Acetals Using Dialkylboron Bromide: Evidence for Stereoselectivity Downstream from Ring Fission

✍ Scribed by Guindon, Yvan; Ogilvie, William W.; Bordeleau, Josée; Cui, Wei Li; Durkin, Kathy; Gorys, Vida; Juteau, Hélène; Lemieux, René; Liotta, Dennis; Simoneau, Bruno; Yoakim, Christiane

Book ID
120511364
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
188 KB
Volume
125
Category
Article
ISSN
0002-7863

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Opening of Tartrate Acetals Using Dialky
Opening of Tartrate Acetals Using Dialkylboron Bromide: Evidence for Stereoselectivity Downstream from Ring Fission.
✍ William W. Ogilvie; et al. et al. 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 33 KB

Opening of Tartrate Acetals Using Dialkylboron Bromide: Evidence for Stereoselectivity Downstream from Ring Fission. -The opening of acetals derived from tartaric esters and amides using Br-BMe2 as Lewis acid and R2Cu(CN)Li2 as alkylating agent is a useful method to prepare chiral secondary alcohols