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Opening of metal carbonyl cluster complexes by ligand addition. Synthesis and structural characterization of osmium cluster Os3(CO)11(.mu.-CNCF3)2, a stabilized derivative of the hypothetical complex Os3(CO)13

✍ Scribed by Adams, Richard D.; Chi, Yun; DesMarteau, Darryl D.; Lentz, Dieter; Marschall, Robert

Book ID: 125888039
Publisher: American Chemical Society
Year: 1992
Tongue: English
Weight: 294 KB
Volume: 114
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00031a071

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## Abstract A direct and high‐yield synthetic route for a novel dodecanuclear osmium‐rhodium mixed‐metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an “electron reservoir”. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,