Opening and Addition Modes in Propagation During Radical Polymerization of Fumaric and Maleic Derivatives
✍ Scribed by Matsumoto, Akikazu; Shimizu, Keiichi; Otsu, Takayuki
- Book ID
- 118247132
- Publisher
- Taylor and Francis Group
- Year
- 1997
- Tongue
- English
- Weight
- 614 KB
- Volume
- 34
- Category
- Article
- ISSN
- 1060-1325
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Ethyl-2-(2-cyano-2-ethylthio)-ethyl-propenoate (ECEP) was synthesized and examined as free-radical addition-fragmentation chain transfer agent (AFCTA) in the bulk polymerization of methyl methacrylate (MMA) and styrene at various temperatures. A better chain transfer constant (C tr ) was observed fo