✦ LIBER ✦

Open-Framework Zinc Phosphates Synthesized in the Presence of Structure-Directing Organic Amines

✍ Scribed by Devicharan Chidambaram; S. Neeraj; Srinivasan Natarajan; C.N.R. Rao

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 579 KB
Volume: 147
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.1999.8206

No coin nor oath required. For personal study only.

✦ Synopsis

Four open-framework zinc phosphates have been synthesized in the presence of structure-directing organic amines. Crystal data: compound I, [NH 3 (CH 2 ) 2 NH 3 ' Zn 2 (HPO 4 ) 2 (H 2 PO 4 ) 2 ], monoclinic, space group ‫؍‬ P2 1 /c (No. 14), a ‫؍‬ 16.420(2) A > , b ‫؍‬ 7.826(1) A > , c ‫؍‬ 14.640(1) A > , ‫؍‬ 116.47(1)3, V ‫؍‬ 1684.05(2) A > 3 , Z ‫؍‬ 4, M ‫؍‬ 578.8(1), D calc ‫؍‬ 2.22 g cm ؊3 , MoK , R F ‫؍‬ 0.05; compound II, [NH 3 (CH 2 ) 2 NH 3 'Zn(HPO 4 ) 2 ], monoclinic, space group ‫؍‬ P2 1 /c (No. 14), a ‫؍‬ 5.161(1) A > , b ‫؍‬ 15.842(2) A > , c ‫؍‬ 12.027(2) A > , ‫؍‬ 92.36(2)3 3, V ‫؍‬ 982.41(1) A > 3 , Z ‫؍‬ 4, M ‫؍‬ 319.45(1), D calc ‫؍‬ 2.16 g cm ؊3 , MoK , R F ‫؍‬ 0.06; compound III, [NH 3 CH 2 CH(OH)CH 2 NH 3 ' Zn 2 (HPO 4 ) 3 ], monoclinic, space group ‫؍‬ P2 1 /c (No. 14),

📜 SIMILAR VOLUMES

Combinatorial Approach for the Hydrother

Combinatorial Approach for the Hydrothermal Syntheses of Open-Framework Zinc Phosphates.

✍ Yu Song; Jihong Yu; Guanghua Li; Yi Li; Yu Wang; Ruren Xu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

Amine Phosphates as Intermediates in the

Amine Phosphates as Intermediates in the Formation of Open-Framework Structures

✍ S. Neeraj; Srinivasan Natarajan; C. N. R. Rao 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 279 KB 👁 2 views

ChemInform Abstract: Formation of One-,

ChemInform Abstract: Formation of One-, Two-, and Three-Dimensional Open-Framework Zinc Phosphates in the Presence of a Tetramine.

✍ Amitava Choudhury; Srinivasan Natarajan; C. N. R. Rao 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

The Hierarchy of Open-Framework Structur

The Hierarchy of Open-Framework Structures in Metal Phosphates and Oxalates.

✍ Srinivasan Natarajan; C. N. R. Rao 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB 👁 2 views

Cyclam as a Structure-Directing Agent in

Cyclam as a Structure-Directing Agent in the Crystallization of Aluminophosphate Open Framework Materials from Fluoride Media

✍ Paul S. Wheatley; Russell E. Morris 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 467 KB

Two aluminofluorophosphates have been synthesized using 1,4,8,11-tetraazacyclotetradecane (cyclam) as a structure-directing agent (SDA). The two materials were synthesized hydrothermally and their structures solved by microcrystal diffraction using synchrotron radiation. In both cases, the SDA has b

ChemInform Abstract: A Novel Chiral Poro

ChemInform Abstract: A Novel Chiral Porous Metal—Organic Framework: Asymmetric Ring Opening Reaction of Epoxide with Amine in the Chiral Open Space.

✍ Koichi Tanaka; Shinji Oda; Motoo Shiro 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v