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Only the copper(I) ion coordinated to the .pi.-system of the nitrile group activates upon collision carbon-hydrogen and carbon-carbon bonds of nitriles

✍ Scribed by Lebrilla, Carlito B.; Drewello, Thomas.; Schwarz, Helmut.

Book ID: 126334501
Publisher: American Chemical Society
Year: 1987
Tongue: English
Weight: 294 KB
Volume: 6
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00154a030

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📜 SIMILAR VOLUMES

Origin of the distinctly different gas-p

Origin of the distinctly different gas-phase chemistry of linear and .alpha.-branched aliphatic nitriles with bare iron(I) ions. Evidence for oxidative addition of the carbon-cyano bond to iron(+), new mechanisms for the reductive eliminations of alkanes, and a demonstration of consecutive carbon-hydrogen/carbon-carbon bond activations of different sites of flexible molecules

✍ Czekay, Gregor.; Drewello, Thomas.; Eller, Karsten.; Zummack, Waltraud.; Schwarz 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 995 KB