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One-step synthesis of poly(alkyl methacrylate)-b-polyester block copolymers via a dual initiator route combining RAFT polymerization and ROP

✍ Scribed by Young Chang Yu, Guoxue Li, Hyun Uk Kang, Ji Ho Youk

Book ID: 120795435
Publisher: Springer
Year: 2012
Weight: 400 KB
Volume: 290
Category: Article
ISSN: 0340-255X
DOI: 10.1007/s00396-012-2788-6

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## Abstract Diblock copolymers of poly(L‐lactide)‐__block__‐poly(methyl methacrylate) (PLLA‐__b__‐PMMA) were synthesized through a sequential two‐step strategy, which combines ring‐opening polymerization (ROP) and atom transfer radical polymerization (ATRP), using a bifunctional initiator, 2,2,2‐tr