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One-Step Synthesis of Organolanthanide(II) Complexes from the Metal

โœ Scribed by Dipl.-Chem. Anja Recknagel; Dr. Frank T. Edelmann

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
252 KB
Volume
30
Category
Article
ISSN
0044-8249

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The platina-b-diketones [Pt 2 {(COR) 2 H} 2 (l-Cl) 2 ] (1, R = Me a, Et b) react with phosphines L in a molar ratio of 1 : 4 through cleavage of acetaldehyde to give acylplatinum(II) complexes trans-[Pt(COR)Cl(L) 2 ] (2) (R/L = Me/P(p-FC 6 H 4 ) 3 a, Me/P(p-CH 2 =CHC 6 H 4 )Ph 2 b, Me/P(n-Bu) 3 c, E