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One-step Synthesis of Dialkyl 1,2-Dihydroquinoline-2,3-dicarboxylates. A Vinyltriphenylphosphonium Salt Mediated Intramolecular Wittig Reaction†

✍ Scribed by Yavari, Issa; Ramazani, Ali; Esmaili, Abbas Ali

Book ID
118068220
Publisher
Science Reviews 2000 Ltd
Year
1997
Tongue
English
Weight
84 KB
Volume
6
Category
Article
ISSN
0308-2342

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An Efficient One-Pot Synthesis of Dialkyl 2,5-Dihydrofuran-2,3dicarboxylates Mediated by Vinyltriphenylphosphonium Salt. -Functionalized 2,5-dihydrofurans (III) (9 examples) are prepared in fairly good yields by PPh 3 -mediated reaction of dialkyl acetylenedicarboxylates (I) with 2-hydroxyketones (I