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One-step synthesis of 2,2′-thienylpyrroles from methyl 2-thienyl ketoxime and acetylene

✍ Scribed by B. A. Trofimov; A. I. Mikhaleva; R. N. Nesterenko; A. N. Vasil'ev; A. S. Nakhmanovich; M. G. Voronkov


Book ID
112335561
Publisher
Springer US
Year
1977
Tongue
English
Weight
66 KB
Volume
13
Category
Article
ISSN
0009-3122

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Pyrroles from ketoximes and acetylene. 4
✍ S. E. Korostova; R. N. Nesterenko; A. I. Mikhaleva; S. G. Shevchenko; G. A. Kala 📂 Article 📅 1991 🏛 Springer US 🌐 English ⚖ 439 KB

We have studied the reaction of 1-vinyl-2-(2.furyl). and -(2-thienyl)pyrroles with trifluoroacetic anhydride, with hydrogen in the presence of catalysts (Raney nickel, palladium black, palladous chloride), with propargyl alcohol in electrophUic conditions [catalysis by perfluorobutyric acid in the s