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One-step synthesis and electrochemically enhanced cation-binding properties of novel “quinonoid crown ethers”

✍ Scribed by Kazuhiro Maruyama; Hajime Sohmiya; Hiroshi Tsukube


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
225 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis


Novel crown ethers bearing reducible quinonoid functions were readily prepared by applying oxidative C-C coupling to the ringclosure step of acyclic polyether precursors. They showed highly


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Synthesis and alkali cation binding prop
✍ Masamitsu Shirai; Mitsuru Kuwahara; Makoto Tanaka 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 586 KB

Polymers, with differently sized crown ethers as alkali cation binding sites and photodimerizable cinnamoyl moieties in their side-chains, were prepared by the cationic copolymerization of the corresponding monomers. The form of the crown-cation complexes (l : l or 2 : l) was studied by measuring qu