One-step syntheses of macrocyclic compounds: A short review
β Scribed by Krzysztof E. Krakowiak; Reed M. Izatt; Jerald S. Bradshaw
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2001
- Tongue
- English
- Weight
- 339 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-152X
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β¦ Synopsis
Abstract
Macrocyclic ligands have been prepared by various oneβstep cyclooligomerization processes. This short review covers oneβstep cyclization reactions involving the formation of four to twenty or more new covalent bonds. The new macrocycles reviewed include cyclophanes, biscrown ethers, cryptands, macrolides, cage compounds, calixarenes, homocalixarenes, cucubiturils, and supercryptands all prepared by oneβstep syntheses.
π SIMILAR VOLUMES
A convienent one-pot synthesis of macrocycles containing a bis(thiocarbamoyl) derivatives 3. In the final step, a ringclosure reaction using a large number of Ξ±,Ο-dielectrophilic tetraaminoethene substructure is described. Starting from oxalic amidines 1, reduction with lithium and subsequent buildi