One-step stereospecific conversion of alcohols into dithiocarbamates: A smooth pathway for the introduction of a sulphur functionality
โ Scribed by P. Rollin
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 120 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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Alcohols are converted in a one-step procedure into ally1 ethers under neutral conditions, using ally1 ethyl carbonate in the presence of a catalytic amount of palladium (0). Anomeric hydroxyls are selectively allylated in the presence of other hydroxyl groups. Ally1 groups have been found to be of