One-step preparation of some 2-isopropenyl-2,3-dihydronaphtho-[2,3-b]furan-4,9-diones
✍ Scribed by Seiji Yamaguchi; Toshiharu Katsuki; Hajime Yokoyama; Yoshiro Hirai
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2001
- Tongue
- English
- Weight
- 48 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-152X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Some 2‐isopropenyl‐2,3‐dihydronaphtho[2,3‐b]furan‐4,9‐diones la‐f,b',f were prepared by one‐step cyclizations of 2‐hydroxy‐1,4‐naphthoquinones 2a‐f with 1,4‐dibromo‐2‐methyl‐2‐butene (3).
📜 SIMILAR VOLUMES
## Abstract 4,9‐Dimethoxynaphtho[2,3‐__b__]furan 9 was obtained in 91% yield __via__ the reductive methylation of naphtho[2,3‐__b__]furan‐4,9‐dione 2. After treatment of 9 with butyllithium, the mixture was allowed to react with __N,N__‐dimethylacetamide, followed by oxidization with cerium(IV) dia
## Abstract 2‐Chloronaphtho[2,3‐__b__]furan‐4,9‐dione 4 was allowed to react with pyrrolidine to produce 2‐(1‐pyrrolidinyl)naphtho[2,3‐__b__]furan‐4,9‐dione 8 in 64% yield. In a similar manner, the reaction of 4 with cyclic amines (piperidine, morpholine, 4‐substituted piperazines, __etc__.) gave t