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One-Step Palladium-Catalyzed Synthesis of Substituted Dihydrofurans from the Carbonate Derivatives of γ-Hydroxy-α,β-unsaturated Sulfones

✍ Scribed by Garrido, José L.; Alonso, Inés; Carretero, Juan C.


Book ID
126394135
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
192 KB
Volume
63
Category
Article
ISSN
0022-3263

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Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet