One-step functionalization of graphene with cyclopentadienyl-capped macromolecules via Diels–Alder “click” chemistry

Functionalization of Fullerenes with Cyc

Functionalization of Fullerenes with Cyclopentadienyl and Anthracenyl Capped Polymeric Building Blocks via Diels–Alder Chemistry

✍ Leena Nebhani; Christopher Barner-Kowollik 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB

## Abstract Cyclopentadienyl (Cp) capped polymers [polyethylene glycols (PEGs), $\overline M \_{\rm n}$ = 2 000 g · mol^−1^], react readily with fullerenes in a 1:1 molar ratio (relative to the amount of fullerenes and Cp‐end groups) at ambient temperature within 5 min in the absence of any catalys