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One-step biomimetic conversion of a furanoheliangolide into an eremantholide using Stryker’s reagent

✍ Scribed by Daiane Cristina Sass; Vladimir Constantino Gomes Heleno; João Luis Callegari Lopes; Mauricio Gomes Constantino


Book ID
108284968
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
180 KB
Volume
49
Category
Article
ISSN
0040-4039

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✍ Takeshi Kinoshita; Koji Ichinose; Ushio Sankawa 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 173 KB

Sunsmuryr One-step &em&I conversion of flavanones into isoflavones by use of thallium trim&ate (TIN) is reported, and the mechanism of a 2.3~aryl migration in this reaction is discussed in relation to in vivo reamngement process of flavanone precursors in the isoflavone biosynthesis.