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“One-pot” synthesis of (Z)-2-aryl-1-(2-cyanoethyl)ethenylphosphonates via hexamethylphosphoramide-promoted sequential transformation

✍ Scribed by Guoping Wang; Yanchang Shen


Book ID
102230761
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
121 KB
Volume
13
Category
Article
ISSN
1042-7163

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✦ Synopsis


Abstract

(Z)‐2‐Aryl‐1‐(2‐cyanoethyl)ethenylphosphonates were synthesized by the hexamethylphosphoramide‐promoted sequential transformation of tetra‐alkyl methanediphosphonates, by the action of potassium tert‐butoxide, and then by acrylonitrile and aldehydes. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:116–119, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10004


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