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One-Pot Synthesis of Triazole-Linked Glycoconjugates.

✍ Scribed by Srinivas Chittaboina; Fang Xie; Qian Wang


Publisher
John Wiley and Sons
Year
2005
Weight
20 KB
Volume
36
Category
Article
ISSN
0931-7597

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Various a-linked 2,6-dideoxy-ribo-trisaccharides, models for part of the antibiotic kijanimicin, were synthesised by the N-iodosuccinimide method employing different pathways. The efficiency of a sequential synthesis suffered from side reactions of the axial HO-3, which are typical of digitoxosides.