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One-Pot Synthesis of Stable Phosphorus Ylides Using CH-Acid Compounds

โœ Scribed by Maghsoodlou, Malek Taher; Khorassani, Sayyed Mostafa Habibi; Hazeri, Nourollah; Nassiri, Mahmoud

Book ID
120173913
Publisher
Taylor and Francis Group
Year
2006
Tongue
English
Weight
261 KB
Volume
181
Category
Article
ISSN
1042-6507

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One-pot synthesis of stable phosphonium
One-pot synthesis of stable phosphonium ylides using 2-aminothiophenol
โœ Abbas Ali Esmaili; Mahnaz Ghereghloo; Mohammad Reza Islami; Hamid Reza Bijanzade ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 99 KB

Protonation of reactive 1:1 intermediates produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylate by 2-aminothiophenol leads to vinylphosphonium salts, which undergo Michael addition with thiophenolate anion to produce highly functionalized phosphonium ylides in excell