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One-pot synthesis of N-[(trimethylsilyl)methyl]imines and (trimethylsilyl)methyl-substituted heterocumulenes from (trimethylsilyl)methyl azide

โœ Scribed by Tsuge, Otohiko; Kanemasa, Shuji; Matsuda, Koyo


Book ID
119993177
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
537 KB
Volume
49
Category
Article
ISSN
0022-3263

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Synthesis and Structures of [(Trimethyls
โœ William Clegg; Ben Conway; Alan R. Kennedy; Jan Klett; Robert E. Mulvey; Luca Ru ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 388 KB

Trimethylsilyl)methyl]sodium [NaCH 2 SiMe 3 ] (1) was prepared by a metathesis reaction of [(trimethylsilyl)methyl]lithium [LiCH 2 SiMe 3 ] with sodium tert-butoxide in n-hexane. Polydentate donors such as N,N,Nะˆ,Nะˆ-tetramethylethylenediamine (TMEDA) and N,N,Nะˆ,Nะˆะˆ,Nะˆะˆ-pentamethyldiethylenetriamine