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One-pot synthesis of functionalized thioureas by reaction of benzoyl isothiocyanates, secondary amines, and alkyl propiolates

✍ Scribed by Issa Yavari; S. Zahra Sayyed-Alangi; Maryam Sabbaghan; Rahimeh Hajinasiri; Nasir Iravani


Book ID
106214215
Publisher
Springer Vienna
Year
2008
Tongue
English
Weight
157 KB
Volume
139
Category
Article
ISSN
0026-9247

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One-Pot Synthesis of Tetraalkyl Benzene-
✍ Issa Yavari; Loghman Moradi; Anvar Mirzaei πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 73 KB

## Abstract Alkyl 2‐nitroethanoates react with alkyl propiolates in the presence of triphenylphosphine (Ph~3~P) in a mechanistically unprecedented reaction to afford tetraalkyl benzene‐1,2,3,5‐tetracarboxylates in moderate yields (36–42%).