One-pot diastreoselective synthesis of highly functionalized cyclohexenones: 2-oxo-N,4,6-triarylcyclohex-3-enecarboxamides
β Scribed by Mousavi, Mir Rasul; Maghsoodlou, Malek Taher; Habibi-Khorassani, Sayyed Mostafa
- Book ID
- 125849026
- Publisher
- Springer
- Year
- 2014
- Tongue
- English
- Weight
- 439 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1381-1991
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π SIMILAR VOLUMES
2-(Arylamino)-4-oxo-4H-chromene-3-carbaldehyde 3 (R 2 = aryl) produces 12H-chromeno[2,3-b]quinolin-12-one 4 when treated with sarcosine, piperidine or diethylamine, but produces 3,3 0 -methylenebis(2-arylamino-4H-chromen-4-one) 8 when treated with the same amine in the presence of an excess of forma
## Abstract magnified image The reactive zwitterionic 1β:β1 intermediate **6** generated __in situ__ from the reaction between an isocyanide **2** and a dialkyl acetylenedicarboxylate (=dialkyl butβ2βynedioate) **3** was trapped by an __N__βarylmaleimide or βphthalimide **4** to produce a highly f