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One Pot Diastereoselective Synthesis of New Chiral Spiro-1,3,4-thiadiazoles and 1,4,2-Oxathiazoles from (1R)-Thiocamphor.

โœ Scribed by Amal Feddouli; Moulay Youssef Ait Itto; Aissa Hasnaoui; Didier Villemin; Paul-Alain Jaffres; Jana Sopkova-De Oliveira Santos; Abdelkhalek Riahi; Francois Huet; Jean-Claude Daran


Publisher
John Wiley and Sons
Year
2005
Weight
20 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract 5โ€substituted 4โ€(4โ€chlorophenyl)โ€4Hโ€1,2,4โ€triazolโ€3โ€thiones **3** and 2โ€substituted 5โ€(4โ€chlorophenylamino)โ€1,3,4โ€thiadiazoles **4** were prepared from the intermediate thiosemicarbazides **2** under basic and acidic conditions, respectively. The thiosemicarbazides, in turn, were prepar