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One-Pot Desilylation/Dimerization of Terminal Alkynes by Ruthenium and Acid-Promoted (RAP) Catalysis

✍ Scribed by Chiara Pasquini; Mauro Bassetti


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
187 KB
Volume
352
Category
Article
ISSN
1615-4150

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## Abstract 9,9‐Bis(2′‐ethylhexyl)‐2,7‐diethynylfluorene (**1**) or 1‐(2′‐ethylhexyloxy)‐2,5‐diethynyl‐4‐methoxybenzene (**2**) react in the presence of the [{RuCl(μ‐Cl)(__p__‐cymene)}]~2~/AcOH catalytic system to yield the corresponding poly(aryleneethynylenevinylene) π‐conjugated homopolymers, fe