One-pot, additive-free preparation of functionalized polyurethanes via amine–thiol–ene conjugation
✍ Scribed by Espeel, Pieter; Goethals, Fabienne; Driessen, Frank; Nguyen, Le-Thu T.; Du Prez, Filip E.
- Book ID
- 120035065
- Publisher
- The Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 932 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1759-9954
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AbstractÐA new copper(I)-mediated method for effecting intramolecular conjugate addition of alkenyl functions to a,b-unsaturated ketone systems is reported. Treatment of the substrates 14, 15, 19±21, 22 and 23 with 2.5 equiv. of CuCl in DMF at room temperature affords excellent yields of the corresp
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