One-phase supported titanium-based catalyst for polymerization of ethylene. IV. Effect of alkyl group at organoaluminium compound on catalyst performance

✍ Scribed by Pavel Šindelář; Dalibor Matula; Jaroslav Holeček

• Publisher: John Wiley and Sons
• Year: 1996
• Tongue: English
• Weight: 805 KB
• Volume: 34
• Category: Article
• ISSN: 0887-624X
• DOI: 10.1002/(sici)1099-0518(199608)34:11<2163::aid-pola9>3.0.co;2-#

✦ Synopsis

The effect of a basic layer (Si02-R3Al intermediate) in the one-phase silica supported titanium-based catalyst was investigated using the simple model catalyst systems obtained by reacting the activated silica gel consecutively with R3Al and TiC14. Mode of the interaction of SiO, with R3Al-resulting in the formation of the basic layer-was observed via analysis of the concentration of the unreacted OH groups on the silica surface employing IR spectroscopy and via analysis of the concentration of aluminium in solvent using AA spectroscopy. It was found that nature of the alkyl group in R3Al modified the structure of the basic layer, thus influencing the catalyst performance including the concentration of both the sum of Ti2+ and Ti3+ and the ESR-active T i (111) centers. The sum of Ti2+ and Ti3+ ranged from 45 to 52 mol % and the amount of the ESR-active T i (111) species ranged from 6 to 17 mol % of the all titanium content. A significant effect of alkyl group at organoaluminium compound on the molecular weight distribution of the resulting polymer was observed.