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One-particle ionization energies from correlated wavefunctions: Applications to Be

✍ Scribed by Robert C. Morrison


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
305 KB
Volume
62
Category
Article
ISSN
0009-2614

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✦ Synopsis


One-particlr ionization energies are calcuhted from .m N-pzticle reference ground state configurntion ïnterxtion wavefunction b) sohing rhe secular equation in 3 space of (N -I)-particle functions formed b) annïhtlation of orbitais Qi from the reference \iavefunction. qI(V-I) = N"'I~~IX~,,)~~~)(.~t . X2V)dX1\r. The Is and 2s ionization energes obtained from 3 95 confi~uration ground state wawfunction for Be sre 1.701 and 0328 JU, respectiWl&'.