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One-electron reactions in biochemical systems as studied by pulse radiolysis. II. Riboflavine

✍ Scribed by Land, Edward J.; Swallow, Albert J.

Book ID
118745773
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
744 KB
Volume
8
Category
Article
ISSN
0006-2960

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πŸ“œ SIMILAR VOLUMES

One-electron oxidation and demetalation
One-electron oxidation and demetalation of metalloporphyrins and chlorophyll a in dichloroethane solutions as studied by pulse radiolysis
✍ Haim Levanon; P. Neta πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 356 KB

Formation of cation radicals by pulse radiolysis of metalloporphyrins and chlorophyll a in 1,2dichIoroethane is reported. Demetalation of the metalloporphyrin by radiolytically produced HCl is also observed. Rate constants for demetalation of ZnTPP and Chl a are 1 .I X IO8 and = 3 X IO8 h!-' s-I\_ O