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One-Electron Oxidation of Alcohols by the 1,3,5-Trimethoxybenzene Radical Cation in the Excited State during Two-Color Two-Laser Flash Photolysis

✍ Scribed by Cai, Xichen; Sakamoto, Masanori; Fujitsuka, Mamoru; Majima, Tetsuro


Book ID
127264817
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
80 KB
Volume
111
Category
Article
ISSN
1089-5639

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CO-Bond Cleavage of Esters with a Naphth
✍ Xichen Cai; Masanori Sakamoto; Minoru Yamaji; Mamoru Fujitsuka; Tetsuro Majima 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB 👁 1 views

## Abstract A CO‐bond cleavage of esters having a naphthyl group, NpCO‐OR and RCO‐ONp (Np=α‐ and β‐naphthyl (^α^Np and ^β^Np, respectively), R=Ph and Me), was found during the two‐color two‐laser flash photolysis in acetonitrile. The CO‐bond cleavage occurred when NpCO‐OR and RCO‐ONp were excited